A look at the basics of carbon sequestration

 
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Jan 20, 2008 - 08:13:10 CST
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(CO2)

That's how one version of carbon sequestration works.

The other is more natural. Circle-of-life stuff that has been happening forever.

Both methods reduce the amount of carbon dioxide that is released to the atmosphere. You hear a lot about carbon sequestration or carbon capture these days, techniques that could mean a great deal for North Dakota in the near future. In addition to reducing emissions - something that could soon be required under federal law - stored CO2 can also help pull more money out of the ground by releasing oil and coal-bed methane that traditional wells can't reach. More on that later.

Right now, let's get to the bottom of what the terms mean and how it all works. Carbon management, which includes the capture and storage of carbon dioxide, is a highly complicated process. But it's pretty easy to understand in theory.

First, you need to know that carbon sequestration basically happens in two ways - direct and indirect.

The direct capture of carbon dioxide usually means grabbing the gas before it leaves its man-made source, like a coal-fired power plant. It's then compressed for storage in underground traps. Bismarck's Basin Electric Power Cooperative owns a coal-gasification plant near Beulah that captures more CO2 than any other single source in the world.

Indirect capture refers to the natural carbon cycle, where corn or switch grass or the wild prairie rose "breathe" in CO2. They exhale the oxygen and keep the carbon to help them grow. This effect can be enhanced by improved land-management practices.

Indirect capture is also known as terrestrial sequestration. Direct capture is often referred to as geologic sequestration.

There is a lot of science behind each method, but if you gloss over that and look at the basics, the steps seem pretty simple.

Geologic sequestration

The idea behind this is pretty new - it's only been practiced in North Dakota for about eight years.

The goal is twofold: First, carbon dioxide is prevented from entering the atmosphere; second, when the gas gets stored underground it can repressurize oil, allowing operators to extract more black gold from what had been a dying oil field.

That's what's happening at Basin's Dakota Gasification Co., which sends nearly 9,000 tons of captured CO2 through a pipeline to Saskatchewan every day. The result is millions of dollars in CO2 sales for DGC and many millions more for EnCana, the oil company that uses the CO2 to enhance its recovery operations by 10,000 barrels a day.

That economic possibility, coupled with environmental concerns about global warming, have spurred the interest in geologic sequestration.

In the last two years, the U.S. Department of Energy has invested $80 million to study sequestration options in a region that includes North Dakota. The recipient of the money, the Plains CO2 Reduction Partnership, has said the geology in North Dakota's oil patch is promising for the large-scale storage of carbon dioxide.

But how will all that work?

Well, the first thing that's needed is the technology to capture carbon dioxide. One of the problems is an apparatus doesn't yet exist that can capture carbon from the largest single source in North America - coal-fired power plants.

What happens at smaller commercial sites, like DGC, is the carbon dioxide gets removed from the waste stream and collected in a contactor tower. It works like blowing air through a straw into a glass of water. The CO2 from your breath goes into the water and makes bubbles. Instead of water in the towers, though, they use different solvents to absorb the gas. It's then compressed so it can move through a pipeline to the point where it will go in the ground. How much the gas is compressed depends on how far underground it's going.

The ideal underground home for carbon dioxide is a natural geologic formation where other carbons get trapped. That's why oil fields and unminable coal beds work so well. There are several layers of traps and seals that prevent the buoyant gas from leaking to the surface. Deep underground saline formations, like those scouted in the Williston Basin, also have the potential to make good storage sites.

While underground, the CO2 dissolves in oil or water, adheres to rock and mineralizes. Some of it can stay in gas form.

Another benefit to geologic sequestration is enhanced recovery of coal-bed methane. The methane molecules like to stick to coal; but coal likes CO2 better. There is only so much surface area on the coal, so when the spots newly taken by CO2 are occupied, the methane must go elsewhere. One other place is up through the methane well. Coal-bed methane is the fastest growing source of natural gas in the country, according to the PCOR project.

Terrestrial sequestration

The chemical symbol for carbon dioxide - CO2 - isn't the only mash of letters you've heard of that's related to carbon sequestration.

Here are a couple of others: CRP and PLOTS.

Land-management programs like the Conservation Reserve Program and Private Land Open to Sportsmen were created in part to return soils and habitat to their natural conditions. One major byproduct of that: Better carbon storage.

Terrestrial sequestration uses plants' natural ability to capture carbon dioxide and convert it to carbon. When plants die or soil is turned over for farming, some of that carbon gets released to the air, where it forms again with oxygen and makes more CO2.

Common practices that can be implemented include no-till farming, rotational grazing, growing buffer strips along waterways and planting cover crops.

The major advantage of terrestrial sequestration is that it can be implemented almost immediately, without waiting for technology to catch up.
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A look at the basics of carbon sequestration
Comments

RayB wrote on Feb 27, 2008 3:14 PM:

" People, people... go back to your chemistry class dealing with combustion! Don't you realize that when they are sequesting the CO2 under ground, they also bury our precious oxygen... forever! This is insane. Plants are doing a much better job at capturing CO2, plus they give us back the oxygen.

Money and corrupted politicians will kill this world. "

Renewable Energy to FACTS wrote on Jan 21, 2008 8:17 AM:

" What you fail realize in your wind power numbers is that wind is at best 40% efficient, which takes your number up 60%, and that is before any additional transmission gets built at about $1 million per mile. The numbers you refer to for a coal plant include transmission. Please do some more research before you provide your false "FACTS". "

Nancy LaPlaca wrote on Jan 20, 2008 10:19 PM:

" In the 1960's the U.S. Army Corps of Engineers injected 165 million gallons of liquid waste from Rocky Mtn Arsenal, and a study confirmed that the waste injections induced considerable seismic activity: 1,500 seismic events from 1962-67, three above Richter magnitude five.


FACTS: coal-fired power produces 40% of all CO2, 33% of all mercury and 66% of acid rain. In some states like Ohio, EVERY body of water is contaminated with mercury. One in ten (some studies say one in six) women of child-bearing age in the U.S. have so much mercury in their bodies that she is at risk for having a child with serious neurological disorders.
Coal mining wastes are the largest waste stream in the U.S., and coal combustion wastes are second.
2/3 of a coal plant's energy is lost as waste heat.
Nine IGCC (aka "clean" coal) plants have been cancelled or put on hold according to Emerging Energy Research, Oct. 5, 2007, "TECO, Nuon Cancellations Underscore IGCC's Woes." Since the report was issued, 2 more IGCC's have been cancelled: Colorado and Orlando, for a total of at least eleven cancelled IGCCs. The Orlando plant is notable bc it rec'd $235 million in federal funds, which it must now return.
These plants are NOT economic; and although CO2 can be "captured", the entire process, from capture to compression to transportation to re-pressurization to storage is enormously expensive and risky.
Renewable energy is cost-compeititive. Xcel Energy's recently submitted Colorado Resource Plan estimated these capital costs:
- wind-$1645/kW (with Production Tax Credit);
- wind-$2,000/kW (no PTC);
- concentrating solar with 6 hrs thermal storage-$2572;
- IGCC with 50% capture-$3912/kW;
- pulverized coal, dry cooled with 50% capture-$3688/kW.
Energy efficiency is 1-3 cents/kWh! http://www.xcelenergy.com/XLWEB/CDA/0,3080,1-1-1_41994_45385-42116-2_68_135-0,00.html -(go to Vol. 1, p.1-55)

FutureGen -- the so-called "zero emissions" coal plant -- is upt o $6,500/kW -- far more expensive than any other type of generation, including the most expensive solar p.v.

"

frank weber wrote on Jan 20, 2008 1:00 PM:

" Saskatchewan Power canceled their IGCC project when estimated costs for a 450meg plant went from 1.6 billion to over 3.8 billion AND they are sitting atop the wells where the CO2 could go to enhance their oil recovery. Attempting to capture the carbon dioxide is estimated to take from 25 to 40% of the electricity the the plant can generate......which means that even if it REALLY could be done that it would NEVER BE ECONOMICALLY FEASIBLE unless the customer wishes to see his electric bill .......triple, quadruple??
Anyone want to take bets that this liquified gas (compressed 80 times the volume) is going to stay in the ground FOREVER? CO2 plus water equals carbolic acid......how many million tons per year? From how many plants, for how many years? Want to know why this has received so much political support? Go to www.opensecrets.com and look at what Minnesota's legislators have received.
Tooooo bad there is a 350 word limit!!! "

Carol A Overland wrote on Jan 20, 2008 12:20 PM:

" 9,000 tons daily is over 3 million tons annually. That's a lot more than this DOE (NETL) report says was injected:
http://www.netl.doe.gov/publications/proceedings/01/carbon_seq/2a1.pdf

The Mesaba Project, Excelsior Energy's proposed but tanking IGCC (coal gasification) project in northern Minnesota would emit 5.4 million tons annually, and while the Buelah/Weyburn project has injected more than any project in the world, it's not commercially viable...and consider NET CO2 where oil is "recovered" and then burned generating more CO2. Weyburn doesn't really demonstrate anything sufficient to justify more coal burning. "

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